Confidence interval for the sample proportion is
phat +- z*sqrt(phat(1-phat)/n))
The error is determined by the plus or minus part of this expression. If you want a 99% confidence interval, then z = 2.576. Since you expect a 20/80 split, phat = 0.2. And you want this plus or minus number to be less than or equal to 0.04 (4%). So...
2.576*sqrt(0.2(1-0.2)/n) = 0.04
Then solve for n
sqrt(0.2(0.8)/n) = 0.04/2.576 = 0.01553
0.16/n = 0.01553^2 = 0.00024112
n/0.16 = 1/0.00024112 = 4147.36
n = 4147.36*0.16 = 663.5776,
which you should always round up, so you would need a sample of 664 or more to make the error less than or equal to 0.04.
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